The insertion of ethylene and propylene into titanium alkyls is the cornerstone of Ziegler–Natta catalysis, the main source of polyethylene and polypropylene.
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(b) ziegler-natta-type catalysts (stereocatalysts, orientating catalysts), such as a mixture of titanium trichloride and trialkylaluminium, for the preparation of isotactic polypropylene and ethylene-olefin block copolymers;
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