diphenylacetylene oor Spaans
diphenylacetylene
en
(organic chemistry) A colourless crystalline material widely used as a building block in organic chemistry and as a ligand in organometallic chemistry.
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An idealized transformation is the addition of triethylsilane to diphenylacetylene: Et3SiH + PhC≡CPh → Et3Si(Ph)C=CH(Ph) Hydrosilylation is related to hydrogenation, and similar catalysts are sometimes employed for the two catalytic processes.
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Zinc acetate hydroxysalt and surfactant with incorporated palladium metal nanoparticles were tested as potential catalysts in the Sonogashira reaction starting from phenylacetylene and aryl iodides, particularly iodobenzene or 2-iodophenol, giving diphenylacetylene (32% yield of isolated and purified product) or 2-phenylbenzofuran (18%).
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Another demonstration of this reaction type is an alternative route to tamoxifen starting from diphenylacetylene and ethyllithium:[3]
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