organomercurial compounds
compuesto orgánico del mercurio
organomercury oor Spaans
organomercury
en
(organic chemistry) Describing any organic compound containing a carbon to mercury bond
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organomercúrico
en
of an organic compound, containing a carbon to mercury bond
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The intermediate organomercury compound is then treated with sodium borohydride, NaBH4, and an alcohol is produced.
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Important organomercury compounds are the methylmercury(II) cation, CH3Hg+; ethylmercury(II) cation, C2H5Hg+; dimethylmercury, (CH3)2Hg, diethylmercury, and merbromin ("Mercurochrome").
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Dimethylmercury ((CH3)2Hg) is an organomercury compound.
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The method described below can be used to identify and determine organomercury derivatives employed as preservatives in cosmetic products for the eyes.
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MerA is the enzyme mercuric reductase and MerB is organomercurial lyase.
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Organomercury compounds are always divalent and usually two-coordinate and linear geometry.
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Loss of a proton gives an organomercury product, and ( 3 ) reaction with NaBH4 removes the mercury.
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Chemical oxidation of elemental mercury and organomercury compounds is carried out to destroy the organics and to convert mercury so that it forms mercury salts.
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Even more deadly are organomercury compounds—particularly methylmercuries, which contain the CH3Hg1 ion.
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Attack by an alcohol solvent gives an organomercurial ether that can be reduced to the ether.
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The carboxylate salt of the acid is used to enhance solubility of this organomercurial compound.
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“What exactly is the effect of an excessive component of lindane in this organomercurial compound?”
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Reduction of the organomercurial alcohol gives the Markovnikov alcohol: propan-2-ol.
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Moreover, RAC identified that other organomercury compounds might be used as catalysts in the polymer production.
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The content of organomercurial compounds determined by this method is expressed as the percentage by mass (m/m) as mercury in the sample.
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The toxicity of organomercury compounds presents both dangers and benefits.
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The organomercury compounds are complexed with 1,5-diphenyl-3-thiocarbazone.
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Unlike organocadmium and organozinc compounds, organomercury compounds do not react with water.
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IDENTIFICATION AND DETERMINATION OF ORGANOMERCURY COMPOUNDS
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The organomercury compounds appear as coloured spots whose colour is stable, provided the plate is covered by a glass plate immediately the solvent evaporates.
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The first C–H activation reaction is often attributed to Otto Dimroth, who in 1902, reported that benzene reacted with mercury(II) acetate (See: organomercury), but some scholars do not view this reaction as being true C–H activation.
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In many cases, they have leaked out of their original packages and now appear in inventories as contaminated soil or contaminated building materials, often commingled with many other types of chemicals, including non-POPs, organophosphorous substances, metal phosphides, and organomercury and other heavy metal-based pesticides.
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Because of differences in tissue distributions, mercury poisoning's effects will differ depending on whether it has been caused by exposure to elemental mercury, inorganic mercury compounds (as salts), or organomercury compounds.
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When mercury combines with carbon, the compounds formed are called "organic" mercury compounds or organomercurials.
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