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partition function

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generalization of the definition of a partition function in statistical mechanics

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función de partición

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A function that defines how the rows of a partitioned table or index are spread across a set of partitions based on the values of certain columns, called partitioning columns.
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What is the value of the vibrational partition function for T = 298 K?
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Substituting this expression for the canonical partition function into the preceding equation, qN 0 ln b 0V N!
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One can envision each moment of inertia contributing (bhcB)-1>2 to the overall partition function.
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The partitioning for an index is specified by providing both a partitioning function and a partitioning scheme.
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In statistical mechanics, free entropies frequently appear as the logarithm of a partition function.
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The denominator in Equation (31.48) will decrease such that the vibrational partition function will increase.
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However, what if one performed integration instead of summation to evaluate the partition function?
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The second important relationship to establish is that between the internal energy and the canonical partition function.
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This molecular partition function is strictly applicable to a single molecule.
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When evaluating the rotational partition functions, you can assume that the high-temperature limit is valid.
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We thus calculate the vibrational partition function using equation 18.24.
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Before we can consider the complete molecular partition function Q, we need to know what qrot is.
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Solution The first step to solving this problem is construction of the electronic partition function.
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Calculate the partition function of this system at 50, 100, 200, 300, 500, and 1000 K.
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To determine the average energy, the partition function describing this system must be evaluated.
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If this is so, then the rotational partition function of the heteronuclear diatomic gas is easy to calculate.
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But not all object behavioral patterns partition functionality like this.
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Give a load-balanced range partitioning function to divide the values into 5 partitions. b.
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The classical-mechanical formula for the partition function will be given in Sec. 21.11.
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Use the answer from part (a) to determine the rotational partition function.
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The corresponding average energy calculated using this partition function is U = Nhn>(ebhn + 1).
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Divide by the partition function.
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In analogy with statistical mechanics it is also called the partition function.
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Strictly speaking, electronic partition functions must be considered on an individual basis and termby-term.
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With the rotational partition function, we are in a position to explore this relationship in detail.
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940 sinne gevind in 21 ms. Hulle kom uit baie bronne en word nie nagegaan nie.