rate-determining step oor Spaans
rate-determining step
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paso limitante de la velocidad
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voorbeelde
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Voorbeelde moet herlaai word.
Other kinetic evidence identifies the second proton donation as the rate-determining step.
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Here, the rate-determining step is the dissociative adsorption of N2 (step 2 in the above scheme).
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12.69 What distinguishes the rate-determining step from the other steps in a reaction mechanism?
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How does the rate-determining step affect the observed rate law?
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The rate-determining step in an S N1 reaction is the formation of a carbocation and an anion.
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This means that the rate-determining step of the reaction involves only the alkyl halide. 2.
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depending on the rate determining step
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One of the elementary processes may be the rate-determining step.
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Hence, the rate constant k2 of the rate-determining step might be larger than k1.
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How does the rate-determining step of the mechanism respond to this property of the solvent?
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In sulfonation, the rate-determining step is nucleophilic attack of benzene on the +SO3H ion.
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So that thing that was waiting patiently during the rate- determining steps says, hey, there's a carbocation there.
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The nucleophile does not participate until after the rate-determining step has taken place.
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How does a knowledge of the rate-determining step help us write the rate law of a reaction?
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The carbocation intermediate formed in the rate-determining step is planar.
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In Figure 6.2, the rate-determining step is the formation of the intermediate.
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This slowest step is called the rate-determining step.
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Finally, we note that not all reactions have a single rate-determining step.
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Suppose, however, that the rate-determining step is the second step.
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The overall reaction can occur no faster than the speed of the rate-determining step.
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For example, for the reverse of (16.54), the rate-determining step is C → B.
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This entry constitutes the rate-determining step of their action.
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An analogy for the rate-determining step is the flow of traffic along a narrow road.
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What does this tell you about the rate-determining step for nucleophilic aromatic substitution?
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The rate-determining step has its transition state at the highest point on the reaction coordinate.
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297 sinne gevind in 41 ms. Hulle kom uit baie bronne en word nie nagegaan nie.