intramolecular hydrogen bond oor Kroaties
intramolecular hydrogen bond
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If the existence of intramolecular hydrogen bonds can be assumed, the corresponding correction terms (approx. + 0,6 to + 1,0 log Pow units) must be added (1).
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The first line of research includes synthesis of a new type of guanidine bases and superbases characterized by a presence of strong intramolecular hydrogen bonds in their conjugate acids .
Isti ciklushrenWaC hrenWaC
The margin of error will depend on the reliability of the fragment constants used, the ability to recognise intramolecular interactions (e.g. hydrogen bonds) and the correct use of correction terms.
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Stability of tautomers can also be increased by the formation of an intramolecular hydrogen bond.
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It was shown that intramolecular hydrogen bonding pattern was preserved upon introduction of sterically hindered carbamate protecting group (Boc) instead of sterically less demanding acetamide group (Ac)
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It was shown that intramolecular hydrogen bonding pattern was preserved upon introduction of sterically hindered carbamate protecting group (Boc) instead of sterically less demanding acetamide group (Ac) Keywords
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Complementarity of the receptor and anion geometries, as well as the possibility of formation of intramolecular hydrogen bonds was proven to be of considerable importance in determining the complex stabilities.
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7 sinne gevind in 6 ms. Hulle kom uit baie bronne en word nie nagegaan nie.