lithium chloride oor Indonesies
lithium chloride
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(chemistry) the lithium salt of hydrochloric acid, LiCl, used in the electrolytic production of lithium metal, and as a flux
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Litium klorida
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chemical compound
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Lithium chloride and lithium bromide are hygroscopic and are used as desiccants for gas streams.
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In 1855, larger quantities of lithium were produced through the electrolysis of lithium chloride by Robert Bunsen and Augustus Matthiessen.
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Lithia water is defined as a type of mineral water characterized by the presence of lithium salts (as lithium carbonate or lithium chloride).
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Additionally, an effective catalyst for the couplings of alkyl halides is dilithium tetrachlorocuprate (Li2CuCl4), prepared by mixing lithium chloride (LiCl) and copper(II) chloride (CuCl2) in THF.
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In 1937, Rabi, Kusch, Millman and Zacharias used it to measure the magnetic moment of several lithium compounds with molecular beams, including lithium chloride, lithium fluoride and dilithium.
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The discovery of this procedure led to commercial production of lithium in 1923 by the German company Metallgesellschaft AG, which performed an electrolysis of a liquid mixture of lithium chloride and potassium chloride.
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LiPF 6 is produced by the reaction of PCl 5 with lithium fluoride, with lithium chloride as a side product: PCl5 + 6 LiF → LiPF6 + 5 LiCl PCl5 is a dangerous substance as it reacts violently with water.
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The metal is produced through electrolysis from a mixture of fused 55% lithium chloride and 45% potassium chloride at about 450 °C. As of 2015, most of the world's lithium production is in South America, where lithium-containing brine is extracted from underground pools and concentrated by solar evaporation.
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Process Res. Dev.; 2007; 11(3) pp 378 - 388; (Article) doi:10.1021/op060231b The complete reaction sequence is bromination to a haloketone (not displayed), elimination reaction with lithium chloride to an enone, organic oxidation by osmiumtetroxide and lead tetraacetate with ring-opening and finally reduction of the aldehyde to the alcohol with sodium borohydride and intramolecular lactone formation Organic Syntheses, Coll.
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Handbook of Lithium and Natural Calcium Chloride.
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Lithium aluminium hydride (often abbreviated as LAH) arises from reactions of lithium hydride with aluminium chloride.
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Brande also described some pure salts of lithium, such as the chloride, and, estimating that lithia (lithium oxide) contained about 55% metal, estimated the atomic weight of lithium to be around 9.8 g/mol (modern value ~6.94 g/mol).
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The reaction of allyl phenyl ether 1 with sec-butyllithium at −78 °C gives the lithiated intermediate 2 which on heating to −25 °C only shows the rearranged product 5 but not 4 after trapping the lithium alkoxide with trimethylsilyl chloride.
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Lithium and sodium are typically isolated through electrolysis from their liquid chlorides, with calcium chloride typically added to lower the melting point of the mixture.
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For example, when isovaleric acid is treated with thionyl chloride to give isovaleroyl chloride, it can then be reduced via lithium aluminium tri(t-butoxy)hydride to give isovaleraldehyde in 65% yield.
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Instead, the milder lithium aluminium tri(t-butoxy)hydride, which reacts significantly faster with the acid chloride than with the aldehyde, must be used.
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LiAH was first prepared from the reaction between lithium hydride (LiH) and aluminium chloride: 4 LiH + AlCl3 → LiAlH4 + 3 LiCl In addition to this method, the industrial synthesis entails the initial preparation of sodium aluminium hydride from the elements under high pressure and temperature: Na + Al + 2 H2 → NaAlH4 LiAlH4 is then prepared by a salt metathesis reaction according to: NaAlH4 + LiCl → LiAlH4 + NaCl which proceeds in a high yield.
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The reaction of phosphorus pentoxide and PCl5 produces POCl3: 6 PCl5 + P4O10 → 10 POCl3 PCl5 chlorinates nitrogen dioxide to form unstable nitryl chloride: PCl5 + 2 NO2 → PCl3 + 2 NO2Cl 2 NO2Cl → 2 NO2 + Cl2 PCl5 is a precursor for lithium hexafluorophosphate, LiPF6, an electrolyte in lithium ion batteries.
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For example, sodium hydride (NaH) can be prepared from sodium chloride (NaCl) through the following reaction: LiAlH4 + 4 NaCl → 4 NaH + LiCl + AlCl3 LAH also reacts with many inorganic ligands to form coordinated alumina complexes associated with lithium ions.
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19 sinne gevind in 6 ms. Hulle kom uit baie bronne en word nie nagegaan nie.