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lithium soap
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(chemistry) any lithium salt of a fatty acid, made by the reaction of fat with lithium hydroxide; used in the manufacture of lubricating greases
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Lithium soaps are produced in a manner similar to saponification of triglycerides.
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The main components of lithium soaps are lithium stearate and lithium 12-hydroxystearate.
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Lithium soap has the ability to thicken oils, and it is used to manufacture all-purpose, high-temperature lubricating greases.
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The small demand for lithium soaps and lubricating greases was supported by several small mining operations, mostly in the US.
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Grease made with lithium soap ("lithium grease") adheres particularly well to metal, is non-corrosive, may be used under heavy loads, and exhibits good temperature tolerance.
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This use was supported by the fact that lithium-based soaps have a higher melting point than other alkali soaps, and are less corrosive than calcium based soaps.
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Lithium hydroxide is a strong base and, when heated with a fat, produces a soap made of lithium stearate.
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For lubrication, and as form-release agents, soaps derived from lithium are used due to their higher melting points.
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The most useful of the non-detergent soaps are those based on lithium, as they are free of corrosive properties.
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In soap chemistry, heavy metals form insoluble soaps that are used in lubricating greases, paint dryers, and fungicides (apart from lithium, the alkali metals and the ammonium ion form soluble soaps).
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