raceme oor Indonesies
raceme
en
(botany): An inflorescence in which the flowers are arranged along a single central axis.
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With standard SN1 reaction conditions the reaction outcome is retention via a competing SNi mechanism and not racemization and with pyridine added the result is again inversion.
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Raceme
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In 1849, Louis Pasteur discovered that the racemic form of tartaric acid is a mixture of the levorotatory and dextrotatory forms, thus clarifying the nature of optical rotation and advancing the field of stereochemistry.
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For example, a chemical database might store a molecule with stereochemistry unspecified, whereas a chemical registry system requires the registrar to specify whether the stereo configuration is unknown, a specific (known) mixture, or racemic.
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Racemic BCH-189 (the minus form is known as lamivudine) was invented by Bernard Belleau while at work at McGill University and Paul Nguyen-Ba at the Montreal-based IAF BioChem International, Inc. laboratories in 1988 and the minus enantiomer isolated in 1989.
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The stereochemistry of this type of nucleophilic attack is not an issue, when both alkyl substituents are dissimilar and there are not any other controlling issues such as chelation with a Lewis acid, the reaction product is a racemate.
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An alternative pathway for the racemization of these same complexes is the Ray–Dutt twist.
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Acid racemization will be more precise
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Louis Pasteur separates a racemic mixture of two enantiomers by sorting individual crystals, and demonstrates their impact on the polarization of light (1849).
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He also successfully epoxidized (using racemic tartaric acid) a C-86 Buckminster Fullerene ball, employing p-Cresol as solvent.
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Are the flowers —if you can see any— inconspicuous and small, forming a spike, raceme, or panicle?
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The staminate (male) flowers are without either calyx with corolla; they consist simply of stamens, varying in number from two to 10, accompanied by a nectariferous gland and inserted on the base of a scale which is itself borne on the rachis of a drooping raceme called a catkin, or ament.
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Also, Science (August 28, 1981, p. 1003) reports that a skeleton showing an age of 70,000 years by amino acid racemization gave only 8,300 or 9,000 years by radioactive dating.
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The inflorescence is an unbranched and indeterminate terminal raceme measuring 50–100 cm (20–40 in) tall, with flowers that are yellow or white.
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The racemic parent compound racemorphan was first described in a Swiss and US patent application from Hoffmann-La Roche in 1946 and 1947, respectively; a patent was granted in 1950.
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15 sinne gevind in 7 ms. Hulle kom uit baie bronne en word nie nagegaan nie.