substituent group
Substituen
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(chemistry) Any atom, group, or radical substituted for another, or entering a molecule in place of some other part which is removed.
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The hydroxyl substituents may vary considerably; acetyl, lactyl, methyl, sulfate, and phosphate groups have been found.
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The diene component of the Diels–Alder reaction can be either open-chain or cyclic, and it can host many different types of substituents; it must, however, be able to exist in the s-cis conformation, since this is the only conformer that can participate in the reaction.
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The 5-position is less electron deficient and substituents there are quite stable.
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Linked metallocenes can also be formed by introducing several metallocenyl substituents onto a single cyclopentadienyl ligand.
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In the Newman projection, a circle is used to represent a plane perpendicular to the bond, distinguishing the substituents on the front carbon from the substituents on the back carbon.
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R is typically an alkyl or aryl substituent.
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More complex alkenes may be named with the E–Z notation for molecules with three or four different substituents (side groups).
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Activating substituents or activating groups stabilize the cationic intermediate formed during the substitution by donating electrons into the ring system, by either inductive effect or resonance effects.
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When an alkene has more than one substituent (especially necessary with 3 or 4 substituents), the double bond geometry is described using the labels E and Z. These labels come from the German words entgegen, meaning "opposite", and zusammen, meaning "together".
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If both substituents are on the same side of the bond, it is defined as cis-.
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The tetrahedral intermediate of an acyl compound contains a substituent attached to the central carbon that can act as a leaving group.
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5 Substituent Prefix Names Derived from Parent Hydrides".
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And if we want to check it, we could just substitue it back into that original equation, so let's do that, let's substitute...
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SN2 attack may occur if the backside route of attack is not sterically hindered by substituents on the substrate.
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The substituents on aromatic rings affect the rate of this electrophilic aromatic substitution.
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Ions in ionic liquids often have uneven charge distributions, or bulky substituents like hydrocarbon chains, which also play a role in determining the strength of the interactions and propensity to melt.
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However, if chirality or the specific absolute orientation of the substituents needs to be taken into account, knowing the type of addition is significant.
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Likewise, SOCl2 is AX3E1, but because the X substituents are not identical, the X–A–X angles are not all equal.
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However, the actual reaction product is 1,3,5-triethylbenzene with all alkyl groups as a meta substituent.
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Axial and equatorial positions are not distinguished; instead, substituents are positioned directly above or below the ring atom to which they are connected.
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In an example of the SN2 reaction, the attack of Br− (the nucleophile) on an ethyl chloride (the electrophile) results in ethyl bromide, with chloride ejected as the leaving group.: SN2 attack occurs if the backside route of attack is not sterically hindered by substituents on the substrate.
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One alkyl substituent migrates from carbon to the adjacent oxygen atom, replacing the carboxylic acid leaving behind a carbocation.
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The stereochemistry of this type of nucleophilic attack is not an issue, when both alkyl substituents are dissimilar and there are not any other controlling issues such as chelation with a Lewis acid, the reaction product is a racemate.
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It has particular synthetic utility as means of furnishing α,β–unsaturated cyclohexenone systems by elimination of the 1-methoxy substituent after deprotection of the enol silyl ether.
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Such triorganotin hydroxides exist in equilibrium with the distannoxanes: 2 R3SnOH ⇌ R3SnOSnR3 + H2O With only two organic substituents on each Sn centre, the diorganotin oxides and hydroxides are structurally more complex than the triorgano derivatives.
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90 sinne gevind in 9 ms. Hulle kom uit baie bronne en word nie nagegaan nie.