three-center two-electron bond oor Indonesies

three-center two-electron bond

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(chemistry) Any of several forms of extended covalent bond, deficient in one electron, joining three atoms

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electron-deficient chemical bond where three atoms share two electrons
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It is also the simplest example of a three-center two-electron bond system.
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Agostic interaction is a term in organometallic chemistry for the interaction of a coordinatively-unsaturated transition metal with a C−H bond, when the two electrons involved in the C−H bond enter the empty d-orbital of a transition metal, resulting in a three-center two-electron bond.
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The term agostic is reserved to describe two-electron, three-center bonding interactions between carbon, hydrogen, and a metal.
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Two-electron three-center bonding is clearly implicated in the complexation of H2, e.g., in W(CO)3(PCy3)2H2, which is closely related to the agostic complex shown in the figure.
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