toluene oor Indonesies
toluene
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(organic chemistry) A colourless, inflammable liquid hydrocarbon, methylbenzene, CH <sub>3</sub> .C <sub>6</sub> H <sub>5</sub> , used as a solvent, in high-octane fuels and in the production of many chemical compounds.
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Some of the toxic fumes filling the cabins of new cars include benzene, acetone, ethylbenzene, n-hexane, toluene, and xylene isomers —all of which can be dangerous to humans.
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Not all organic solvents are completely miscible, e.g. a mixture of ethylene glycol and toluene may separate into two distinct organic phases.
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Because basic salts are polar and are not soluble in the non-polar solvents used to dissolve most polymers, mixed solvents (e.g. 90:10 toluene/alcohol) are often used.
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It is less soluble in nonpolar solvents such as benzene, toluene, and xylene, and practically insoluble in petroleum ether.
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Transalkylation, as used by the petrochemical industry, is often used to convert toluene into benzene and xylenes.
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Styrene reacts in toluene with sodium to 1,3-diphenylpropane through the intermediate carbanion: Another exception to the rule is found in the Varrentrapp reaction.
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Nitration reactions are notably used for the production of explosives, for example the conversion of guanidine to nitroguanidine and the conversion of toluene to trinitrotoluene.
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TsOH is prepared on an industrial scale by the sulfonation of toluene.
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Until the early 1990s the most common solvents that were used for the ink were toluene and xylene.
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When many aromatic compounds such as benzoic acid and toluene are taken internally, they are converted to hippuric acid by reaction with the amino acid, glycine.
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Motivation for using transalkylation reactions is based on a difference in production and demand for benzene, toluene, and xylenes.
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Toluene is refluxed with sodium-benzophenone desiccant before it is distilled to give pure oxygen- and water-free toluene.
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Polyisocyanates became commercially available in 1952, and production of flexible polyurethane foam began in 1954 using toluene diisocyanate (TDI) and polyester polyols.
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Plants Hawaiian baby woodrose (contains ergine) Morning glory seeds (contains ergine) Jimson weed (Datura, angel's trumpet, thorn apple) Belladonna (deadly nightshade) Salvia divinorum Volatile solvents and gases (inhalants) Toluene, found in glue, paint, thinner, etc. See also toluene toxicity.
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While the first nitration, on the activated toluene ring, can be done at room temperature and with dilute acid, the second one, on the deactivated nitrotoluene ring, already needs prolonged heating and more concentrated acid, and the third one, on very strongly deactivated dinitrotoluene, has to be done in boiling concentrated sulfuric acid.
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The organic Rankine cycle (ORC) uses an organic fluid such as n-pentane or toluene in place of water and steam.
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DIBAL can be prepared by heating triisobutylaluminium (itself a dimer) to induce beta-hydride elimination: (i-Bu3Al)2 → (i-Bu2AlH)2 + 2 (CH3)2C=CH2 Although DIBAL can be purchased commercially as a colorless liquid, it is more commonly purchased and dispensed as a solution in an organic solvent such as toluene or hexane.
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For example, in the disproportionation of toluene, the M/R ratio is 1.
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Earlier, Sabatier had already observed the hydrogenolysis of benzyl alcohol to toluene, and as early as 1906, Padoa and Ponti had observed the hydrogenolysis of furfuryl alcohol.
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Transalkylation can convert toluene, which is overproduced, into benzene and xylene, which are under-produced.
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Ethanol has a synergistic effect when taken in combination with many solvents; for instance, a combination of toluene/benzene and ethanol causes greater nausea/vomiting than either substance alone.
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An example of this is the nitration of toluene during the production of trinitrotoluene (TNT).
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Examples of activated aromatic rings are toluene, aniline and phenol.
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Benzoic acid is produced commercially by partial oxidation of toluene with oxygen.
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This is achieved through a disproportionation reaction of toluene in which one toluene molecule transfers its methyl group to another one.
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34 sinne gevind in 9 ms. Hulle kom uit baie bronne en word nie nagegaan nie.