redox oor Masedonies
redox
en
Describing, or relating to any reaction which oxidation and reduction occur simultaneously
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Оксидационо-редукциона реакција
en
chemical reaction
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In most cases the proton-motive force is generated by an electron transport chain which acts as a proton pump, using the Gibbs free energy of redox reactions to pump protons (hydrogen ions) out across the membrane, separating the charge across the membrane.
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Ruthenocene is analogous to ferrocene structurally, but exhibits distinctive redox properties.
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Of all flavoproteins, 90% perform redox reactions and the other 10% are transferases, lyases, isomerases, ligases.
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In biochemistry, flavin adenine dinucleotide (FAD) is a redox-active coenzyme associated with various proteins, which is involved with several important enzymatic reactions in metabolism.
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In this redox reaction, sulfur is oxidized from +4 to +6, and vanadium is reduced from +5 to +4: V2O5 + SO2 → 2 VO2 + SO3 The catalyst is regenerated by oxidation with air: 4 VO2 + O2 → 2 V2O5 Similar oxidations are used in the production of maleic anhydride, phthalic anhydride, and several other bulk organic compounds.
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There are also redox flavoproteins that non-covalently bind to FAD like Acetyl-CoA-dehydrogenases which are involved in beta-oxidation of fatty acids and catabolism of amino acids like leucine (isovaleryl-CoA dehydrogenase), isoleucine, (short/branched-chain acyl-CoA dehydrogenase), valine (isobutyryl-CoA dehydrogenase), and lysine (glutaryl-CoA dehydrogenase).
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Flavoproteins utilize the unique and versatile structure of flavin moieties to catalyze difficult redox reactions.
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FAD can exist in four different redox states, which are the flavin-N(5)-oxide, quinone, semiquinone, and hydroquinone.
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When driven by an external voltage applied to the electrodes, the ions in the electrolyte are attracted to an electrode with the opposite charge, where charge-transferring (also called faradaic or redox) reactions can take place.
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The redox reaction is relevant to the instability of fuel assemblies at high temperatures.
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The transfer of electrons from a high-energy molecule (the donor) to a lower-energy molecule (the acceptor) can be spatially separated into a series of intermediate redox reactions.
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Warburg’s work with linking nicotinamide to hydride transfers and the discovery of flavins paved the way for many scientists in the 40s and 50s to discover copious amounts of redox biochemistry and link them together in pathways such as the citric acid cycle and ATP synthesis.
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The Pourbaix diagram for vanadium in water, which shows the redox potentials between various vanadium species in different oxidation states, is also complex.
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Depending on the redox conditions it can exist in two inter-convertible forms: a more common oxidized yellow-brown form which is insoluble in water and only slightly soluble in organic solvents, such as pyridine, and a reduced form with bright red color that is more soluble in organic solvents.
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The pair of an oxidizing and reducing agent that are involved in a particular reaction is called a redox pair.
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In general, electrochemistry describes the overall reactions when individual redox reactions are separate but connected by an external electric circuit and an intervening electrolyte.
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In these reactions one compound passes electrons to another (in a redox reaction), releasing energy to fuel the cell's activities.
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Chemical reactions where electrons are transferred directly between molecules and/or atoms are called oxidation-reduction or (redox) reactions.
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In redox reactions, the transferred particle is an electron, whereas in acid-base reactions it is a proton.
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The reverse process in which electrons are released in redox reactions and can be used as electrical energy is possible and used in batteries.
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Gram quantities of various copper salts have been taken in suicide attempts and produced acute copper toxicity in humans, possibly due to redox cycling and the generation of reactive oxygen species that damage DNA.
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Since flavins have multiple redox states they can participate in processes that involve the transfer of either one or two electrons, hydrogen atoms, or hydronium ions.
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In practice, the transfer of electrons will always change the oxidation state, but there are many reactions that are classed as "redox" even though no electron transfer occurs (such as those involving covalent bonds).
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As indicated by its negative redox potential, titanium is thermodynamically a very reactive metal that burns in normal atmosphere at lower temperatures than the melting point.
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Iron is also the metal at the active site of many important redox enzymes dealing with cellular respiration and oxidation and reduction in plants and animals.
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37 sinne gevind in 5 ms. Hulle kom uit baie bronne en word nie nagegaan nie.