ruthenium oor Masedonies
ruthenium
en
a metallic chemical element (symbol Ru) with an atomic number of 44.
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рутениум
en
chemical element
Рутениум
en
chemical element with the atomic number of 44
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The native form of ruthenium is a very rare mineral (Ir replaces part of Ru in its structure).
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Because it hardens platinum and palladium alloys, ruthenium is used in electrical contacts, where a thin film is sufficient to achieve the desired durability.
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In 2012, Masaaki Kitano and associates, working with an organic ruthenium catalyst, demonstrated ammonia synthesis using a stable electride as an electron donor and reversible hydrogen store.
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Heating solutions of ruthenium trichloride in alcohols with triphenylphosphine gives tris(triphenylphosphine)ruthenium dichloride (RuCl2(PPh3)3), which converts to the hydride complex chlorohydridotris(triphenylphosphine)ruthenium(II) (RuHCl(PPh3)3).
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In 1844, Karl Ernst Claus, a Russian scientist of Baltic German descent, showed that the compounds prepared by Gottfried Osann contained small amounts of ruthenium, which Claus had discovered the same year.
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Ruthenium trichloride reacts with carbon monoxide to give many derivatives including RuHCl(CO)(PPh3)3 and Ru(CO)2(PPh3)3 (Roper's complex).
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A new application of ruthenium is as the capping layer for extreme ultraviolet photomasks.
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Ruthenium, osmium, and iridium are considered the minor platinum group metals.
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Ruthenium red, 6+, is a biological stain used to stain polyanionic molecules such as pectin and nucleic acids for light microscopy and electron microscopy.
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These two electronic applications account for 50% of the ruthenium consumption.
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Choosing the name for the new element, Claus stated: "I named the new body, in honour of my Motherland, ruthenium.
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Ruthenium-promoted cobalt catalysts are used in Fischer-Tropsch synthesis.
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A minor application for ruthenium is in platinum alloys and as a chemistry catalyst.
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ruthenium Ru 44
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Il Messaggero reports that this one plant in Arezzo alone recovers a yearly average of some 120 tons of gold, 200 tons of silver, 4 tons of palladium, one ton of platinum, 220 pounds [100 kg] of rhodium, and small quantities of iridium and ruthenium.
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All unstable isotopes of molybdenum decay into isotopes of niobium, technetium, and ruthenium.
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The tip material in modern fountain pens is still conventionally called "iridium", although there is seldom any iridium in it; other metals such as ruthenium, osmium and tungsten have taken its place.
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Some ruthenium complexes absorb light throughout the visible spectrum and are being actively researched for solar energy technologies.
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Ruthenium tetroxide exposes latent fingerprints by reacting on contact with fatty oils or fats with sebaceous contaminants and producing brown/black ruthenium dioxide pigment.
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With similar properties and lower cost than rhodium, electric contacts are a major use of ruthenium.
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Like osmium tetroxide, ruthenium tetroxide is a potent fixative and stain for electron microscopy of organic materials, and is mostly used to reveal the structure of polymer samples.
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Unlike the lighter congener iron, ruthenium is paramagnetic at room temperature, as iron also is above its Curie point.
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Osmium, ruthenium, rhodium, and iridium are insoluble in aqua regia and readily precipitate, leaving the other metals in solution.
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The beta-decaying isotope 106 of ruthenium is used in radiotherapy of eye tumors, mainly malignant melanomas of the uvea.
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Ruthenium is usually found as a minor component of platinum ores; the annual production has risen from about 19 tonnes in 2009 to some 35.5 tonnes in 2017.
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