oxophilicity oor Nederlands

oxophilicity

naamwoord
en
A tendency to form oxides, typically by abstraction of oxygen from organic compounds

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oxofilie

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A combination of silver perchlorate and Lawesson's reagent is able to act as an oxophilic Lewis acid with the ability to catalyze the Diels-Alder reaction of dienes with α,β-unsaturated aldehydes.
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The oxophilicity of cerium imparts strong 1,2-selectivity in reactions with conjugated electrophiles similarly to organolithium reagents.
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Also analogous to the Wittig reagent, the reactivity appears to be driven by the high oxophilicity of Ti(IV).
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