gyromitrin oor Portugees
gyromitrin
en
A toxin and possible carcinogen present in most members of the fungal genus Gyromitra, most notably the false morel Gyromitra esculenta.
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Giromitrina
en
chemical compound
pt
composto químico
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Although the amount of gyromitrin present can be significantly reduced through parboiling, there is evidence that repeated consumption can increase risk of toxicity.
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While some of these species contain little to no gyromitrin, many guidebooks recommend treating them all as poisonous, since their similar appearance and significant intraspecific variation can make reliable identification difficult.
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Several Gyromitra species are traditionally considered very good edibles and several steps are available to remove gyromitrin from these mushrooms and allow their consumption.
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Gyromitrin content can differ greatly in different populations of the same species.
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The method, which involves acid hydrolysis of gyromitrin followed by derivatization with pentafluorobenzoyl chloride, has a minimum detectable concentration equivalent to 0.3 microgram of gyromitrin per gram of dry matter.
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The identity of the toxic constituents eluded researchers until 1968, when acetaldehyde N-methyl-N-formylhydrazone, better known as gyromitrin, was isolated.
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Drying the mushrooms can also reduce the concentration of gyromitrin; ten days of open air desiccation leads to the loss of 90% of gyromitrin.
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If boiling the mushrooms indoors, care should be taken to ensure adequate ventilation, and, if symptoms of gyromitrin poisoning appear, immediately seek fresh air.
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Gyromitrin is volatile and water soluble, and can be mostly removed from the mushrooms by cutting them to small pieces and repeatedly boiling them in copious amounts of water under good ventilation.
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Another important and potentially fatally poisonous mushroom species is Gyromitra esculenta, which contains gyromitrin.
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Most of the gyromitrin must be removed to render false morels edible.
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The gyromitrin is leached into the water where it will remain, therefore the parboiling water must be discarded and replaced with fresh water after each round of boiling.
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Giving pyridoxine to rats poisoned with gyromitrin inhibited seizures, but did not prevent liver damage.
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Strains with much lower concentrations of gyromitrin have been discovered, and the fungus has been successfully grown to fruiting in culture.
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Gyromitrin is a toxin and carcinogen present in several members of the fungal genus Gyromitra, like G. esculenta.
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Raw Gyromitra are toxic due to the presence of gyromitrin, and it is not known whether all of the toxin can be removed by parboiling.
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Even after boiling, small amounts of gyromitrin remain in the mushrooms.
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Poorly ventilated spaces allow vapor to accumulate, resulting in gyromitrin poisoning.
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A lethal dose of gyromitrin has been estimated to be 10–30 mg/kg for children and 20–50 mg/kg in adults.
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Gyromitra esculenta contains levels of the poison gyromitrin that vary locally among populations; although these mushrooms are only rarely involved in poisonings in either North America or western Europe, intoxications are seen frequently in eastern Europe and Scandinavia.
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The toxicity of gyromitrin varies greatly according to the animal species being tested.
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The early methods developed for the determination of gyromitrin concentration in mushroom tissue were based on thin-layer chromatography and spectrofluorometry, or the electrochemical oxidation of hydrazine.
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The identity of the toxic constituents of Gyromitra species eluded researchers until 1968, when N-methyl-N-formylhydrazone was isolated by German scientists List and Luft and named gyromitrin.
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The toxicity is largely due to the MMH that is created; about 35% of ingested gyromitrin is transformed to MMH.
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Gyromitrin is a volatile water-soluble hydrazine compound hydrolyzed in the body into monomethylhydrazine (MMH).
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