acetoacetic acid methyl ester
metilacetoacetato
acetoacetic ester oor Spaans
acetoacetic ester
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acetoacetato de etilo
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Use those groups to alkylate acetoacetic ester, then hydrolyze and decarboxylate.
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Alkylate acetoacetic ester with: (a) PhCH2Br; (b) Br1CH224Br (twice); (c) PhCH2Br, then CH2 “ CHCH2Br 22.53.
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Strategy The acetoacetic ester synthesis yields a methyl ketone by adding three carbons to an alkyl halide.
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The ketone whose H NMR spectrum is shown here was obtained as the product of an acetoacetic ester synthesis.
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Pietro Biginelli (25 July 1860 – 15 January 1937) was an Italian chemist, who discovered a three-component reaction between urea, acetoacetic ester and aldehydes (Biginelli reaction).
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Aluminum Diisopropoxy Acetoacetic Ester Chelate ACA-EAA1 (CAS No. 14782-75-3)
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The ester group in the product must be derived from ethyl acetoacetate.
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The carbon from the ester (now part of the C “ C double bond) should be derived from the ketone of ethyl acetoacetate.
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Tests reveal the administration of a single dose of the synthetic ketone acetoacetate causes a rapid elevation of ketone esters within 30 minutes and is sustained for over four hours.
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