catenane oor Spaans
catenane
en
(organic chemistry) Any compound, especially a hydrocarbon, having two or more rings interconnected like the links of a chain, without a covalent bond.
Vertalings in die woordeboek Engels - Spaans
Catenano
More specifically, catenanes are fundamentally made from interlocked macrocycles.
Más específicamente, los catenanos están formados esencialmente por macrociclos entrelazados.
Geskatte vertalings
Vertoon algoritmies gegenereerde vertalings
voorbeelde
Advanced filtering
Voorbeelde moet herlaai word.
These non-covalent interactions offset some of the entropic cost of association and help position the components to form the desired catenane upon the final ring-closing.
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The molecule was designed without any practical use in mind, although other catenanes may have possible application to the construction of a molecular computer.
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The first is to simply perform a ring-closing reaction with the hope that some of the rings will form around other rings giving the desired catenane product.
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More specifically, catenanes are fundamentally made from interlocked macrocycles.
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When molecular recognition motifs exist in the finished catenane (usually those that were used to synthesize the catenane), the catenane can have one or more thermodynamically preferred positions of the rings with respect to each other (recognition sites).
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The relative movement of the constituents of rotaxanes and catenanes with respect to each other was holding the key to performing a well-defined task and measurable work with this molecular shuttle.
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Catenanes have been synthesized incorporating many functional units, including redox-active groups (e.g. viologen, TTF=tetrathiafulvalene), photoisomerizable groups (e.g. azobenzene), fluorescent groups and chiral groups.
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This "template-directed" approach, together with the use of high-pressure conditions, can provide yields of over 90%, thus improving the potential of catenanes for applications.
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A particularly interesting property of many catenanes is the ability of the rings to rotate with respect to one another.
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In catenane nomenclature, a number in square brackets precedes the word "catenane" in order to indicate how many rings are involved.
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This so-called "statistical approach" led to the first successful synthesis of a catenane; however, the method is highly inefficient, requiring high dilution of the "closing" ring and a large excess of the pre-formed ring, and is rarely used.
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Stoddart has developed highly efficient syntheses of mechanically-interlocked molecular architectures such as molecular Borromean rings, catenanes and rotaxanes utilizing molecular recognition and molecular self-assembly processes.
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When a catenane is synthesized by coordination of the macrocycles around a metal ion, then removal and re-insertion of the metal ion can switch the free motion of the rings on and off.
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There are two primary approaches to the organic synthesis of catenanes.
El capitán no lidera la misiónWikiMatrix WikiMatrix
Much of the research concerning rotaxanes and other mechanically interlocked molecular architectures, such as catenanes, has been focused on their efficient synthesis or their utilization as artificial molecular machines.
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Rotaxanes and catenanes belong to a new class of molecules composed of smaller molecules, which are not connected by chemical bonds and thus can move independently.
¿ Contestarás sinceramente una pregunta?cordis cordis
Examples of mechanically interlocked molecular architectures include catenanes, rotaxanes, molecular knots, and molecular Borromean rings.
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Recently the terminology "mechanical bond" has been coined that describes the connection between the macrocycles of a catenane.
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We have made catenanes with three, four and even five rings - appropriately named the Olympiadane.
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When molecular recognition motifs exist in the finished catenane (usually those that were used to synthesize the catenane), the catenane can have one or more thermodynamically preferred positions of the rings with respect to each other.
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A catenane is a mechanically-interlocked molecular architecture consisting of two or more interlocked macrocycles.
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The first is called a catenane, and this is derived from the Latin word for chain, “catena”.
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This "template-directed" approach, together with the use of high-pressure conditions, can provide yields of over 90%, thus improving the potential of catenanes for applications.
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We isolated replication intermediates (RIs)which were analyzed by high-resolution two-dimensional agarose gel electrophoresis.The results obtained indicated that RIs were more torsionally tensioned when they wereisolated from cells without Topo IV. This observation strongly suggests that forks canswivel in vivo leading to the formation of pre-catenanes as replication progresses.In a second part, we studied different characteristics about replication fork barriers(RFBs).
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A type of mechanical machine which has overtaken catenanes in terms of applications is the rotaxane.
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29 sinne gevind in 7 ms. Hulle kom uit baie bronne en word nie nagegaan nie.