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Enzim-enzim yang mengkatalisasi reaksi dekarboksilasi disebut dekarboksilase atau karboksi-liase (nomor EC 4.1.1).
Enzymes that catalyze decarboxylations are called decarboxylases or, the more formal term, carboxy-lyases (EC number 4.1.1).WikiMatrix WikiMatrix
Reaksi perisiklik juga terdapat dalam beberapa proses biologis: Penataan ulang Claisen pada korismat menjadi prefenat di hampir semua organisme prototropik Pergeseran sigmatropik- dalam transformasi precorrin-8x menjadi asam hidrogenobirinat Pembukaan cincin elektrosiklik fotokimia, non-enzimatik, dan pergeseran hidrida sigmatropik (1,7) dalam sintesis vitamin D Konversi berkatalis isokorismat piruvat liase pada isokorismat menjadi salisilat dan piruvat Reaksi substitusi Reaksi eliminasi ^ Huisgen, R. Kinetics and Mechanism of 1,3-Dipolar Cycloadditions.
Pericyclic reactions also occur in several biological processes: Claisen rearrangement of chorismate to prephenate in almost all prototrophic organisms -sigmatropic shift in the transformation of precorrin-8x to hydrogenobyrinic acid non-enzymatic, photochemical electrocyclic ring opening and a (1,7) sigmatropic hydride shift in vitamin D synthesis Isochorismate pyruvate lyase catalyzed conversion of isochorismate into salicylate and pyruvate Coarctate reaction Woodward–Hoffmann rules Isochorismate Pyruvate Lyase: A Pericyclic Reaction Mechanism?WikiMatrix WikiMatrix
2 sinne gevind in 1 ms. Hulle kom uit baie bronne en word nie nagegaan nie.