labdane oor Spaans
labdane
en
(organic chemistry) A natural bicyclic diterpene with the chemical formula C <sub>20</sub> H <sub>38</sub> , forming the structural core of a wide variety of natural products.
Vertalings in die woordeboek Engels - Spaans
Labdano
en
chemical compound
es
compuesto químico
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Along with these compounds, three labdane and seco-labdane diterpenoids, 8(17),12E,14-labdatrien-18-oic acid [3], 12E-3,4-seco-labda-4(18),8(17),12,14-tetraen-3-oic acid [2], and its methyl ester [1] were isolated from this fraction through preparative HPLC, and their structures were elucidated by HR-FABMS, 1D and 2D NMR analyses.
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A variety of bioactive compounds have been isolated and identified from C. rangiferina, including abietane, labdane, isopimarane, the abietane diterpenoids hanagokenols A and B, ontuanhydride, sugiol, 5,6-dehydrosugiol, montbretol, cis-communic acid, imbricatolic acid, 15-acetylimbricatoloic acid, junicedric acid, 7α-hydroxysandaracopimaric acid, β-resorylic acid, atronol, barbatic acid, homosekikaic acid, didymic acid and condidymic acid.
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The invention provides a series of compounds with labdane-type diterpenoid structure that are capable of activating caspase-8 and therefore induce tumour cell apoptosis.
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The present invention describes a method for producing mero sesquiterpenes, more specifically drimenylbenzenes and drimenylnaphthoquinones, by means of a Diels-Alder reaction between a labdane diterpene and a dienophyl.
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Method for the preparation of mero sesquiterpenes from labdane diterpenes
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ENLACES Y ACCESOS Derechos de autorPolíticasGuía de autoarchivoFAQAfrom sclareol of labdanes di, tri and tetraoxigenados in the ring B to functions at C-6 and C-7.
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The antibacterial activity of 13-epi-sclareol, a labdane type diterpene, isolated from the resinous exudate of Pseudognaphalium heterotrichium and P. cheiranthifolium was tested against four Gram positive and three Gram negative bacteria.
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The compounds obtained in sufficient amount were evaluated as gastroprotective agents in the ethanol-hydrochloric acid induced gastric ulcer model in mice. The cytotoxicity of all new compounds was assessed in three different human cell lines. The results showed that the new amides presented a high gastroprotective effect, that could be related with the configuration of the C-18 carboxylic acid, which differs from other labdanes previously investigated as well as the double bond in the side chain.
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Due to their wide activity profile, alkylation of flavones and flavonols with monoterpenes, such as geranyl and diterpenes of labdane moiety, has been carried out. A wide variety of hybrids has been synthesised and antitumour activity research work done.
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Members contain thyrsiflorin and other scopadulane (labdane) type DITERPENES.
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We have synthesized seven natural labdanes highly oxygenated in ring B having in the side chain groups allyl-hidroxibutenolidas, furans espirobutanolidas, plus some dinorlabdanos tetraoxigenados in ring B, which are advanced intermediates toward forskolin synthesis.
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